ASTM D1159-07R17

Standard Test Method for Bromine Numbers of Petroleum Distillates and Commercial Aliphatic Olefins by Electrometric Titration

WITHDRAWN

About this standard

Languages
English
Type
ASTM
Status
WITHDRAWN
Publication date
01 May 2017
Withdrawn Date

About this training

Summary

< div class=" SectionLevel2" > < p class=" subsec1 cdone2" > < span class=" Head3 cdone" > 1.1< / span> & #x00a0 This test method< span style=" font-style:normal " > < span class=" footnote-link" > 2< / span> < / span> covers the determination of the bromine number of the following materials:

< div class=" SectionLevel3" > < p class=" subsec2 cdone2" > < span class=" Head4 cdone" > 1.1.1< / span> & #x00a0 Petroleum distillates that are substantially free of material lighter than isobutane and that have 90& #8201 % distillation points (by Test Method < span class=" Body-link1 cdone" > D86< / span> ) under 327& #8201 & #x00b0 C (626& #8201 & #x00b0 F). This test method is generally applicable to gasoline (including leaded, unleaded, and oxygenated fuels), kerosine, and distillates in the gas oil range that fall in the following limits:

< div class=" ParaCenter" > < table style=" border-collapse: collapse border-top-style:none border-bottom-style:none " class=" datatable gridtype" width=" 465px" > < col align=" left" width=" 231px" > < / col> < col align=" center" width=" 234px" > < / col> < tbody class=" cdone" > < tr> < td style=" vertical-align:top " > < p style=" text-align:center" class=" tablecell_indented" > 90& #8201 % Distillation Point, & #x00b0 C (& #x00b0 F)

< / td> < td style=" vertical-align:top " > < p style=" text-align:center" class=" tablecell_indented" > Bromine Number, max< span style=" font-style:normal " > < span class=" footnote-link" > 2< / span> < / span>

< / td> < / tr> < tr> < td style=" vertical-align:top " > < p style=" text-align:center" class=" tablecell_indented" > Under 205 (400)

< / td> < td style=" vertical-align:top " > < p style=" text-align:center" class=" tablecell_indented" > 175

< / td> < / tr> < tr> < td style=" vertical-align:top " > < p style=" text-align:center" class=" tablecell_indented" > 205 to 327 (400 to 626)

< / td> < td style=" vertical-align:top " > < p style=" text-align:center" class=" tablecell_indented" > & #x2007 10

< / td> < / tr> < / tbody> < / table> < / div> < / div> < div class=" SectionLevel3" > < p class=" subsec2 cdone2" > < span class=" Head4 cdone" > 1.1.2< / span> & #x00a0 Commercial olefins that are essentially mixtures of aliphatic mono-olefins and that fall within the range of 95 to 165 bromine number (see < span class=" Body-link1 cdone" > Note 1< / span> ). This test method has been found suitable for such materials as commercial propylene trimer and tetramer, butene dimer, and mixed nonenes, octenes, and heptenes. This test method is not satisfactory for normal alpha-olefins.

< div style=" text-align:left " class=" NoteLevel1" >

< span class=" note cdone" style=" text-transform: uppercase " > Note 1:< / span> & #x00a0 < span class=" note cdone" > These limits are imposed since the precision of this test method has been determined only up to or within the range of these bromine numbers.< / span>

< / div> < / div> < / div> < div class=" SectionLevel2" > < p class=" subsec1 cdone2" > < span class=" Head3 cdone" > 1.2< / span> & #x00a0 The magnitude of the bromine number is an indication of the quantity of bromine-reactive constituents, not an identification of constituents therefore, its application as a measure of olefinic unsaturation should not be undertaken without the study given in < span class=" Body-link1 cdone" > Annex A1< / span> .

< / div> < div class=" SectionLevel2" > < p class=" subsec1 cdone2" > < span class=" Head3 cdone" > 1.3< / span> & #x00a0 For petroleum hydrocarbon mixtures of bromine number less than 1.0, a more precise measure for bromine-reactive constituents can be obtained by using Test Method < span class=" Body-link1 cdone" > D2710< / span> . If the bromine number is less than 0.5, then Test Method < span class=" Body-link1 cdone" > D2710< / span> or the comparable bromine index methods for industrial aromatic hydrocarbons, Test Methods < span class=" Body-link1 cdone" > D1492< / span> or < span class=" Body-link1 cdone" > D5776< / span> must be used in accordance with their respective scopes. The practice of using a factor of 1000 to convert bromine number to bromine index is not applicable for these lower values of bromine number.

< / div> < div class=" SectionLevel2" > < p class=" subsec1 cdone2" > < span class=" Head3 cdone" > 1.4< / span> & #x00a0 The values stated in SI units are to be regarded as the standard.

< div class=" SectionLevel3" > < p class=" subsec2 cdone2" > < span class=" Head4 cdone" > 1.4.1< / span> & #x00a0 < span class=" Head4Title cdone" > Exception& #x2014 < / span> The values given in parentheses are for information only.

< / div> < / div> < div class=" SectionLevel2" > < p class=" caveat cdone2" > < span class=" Head3 cdone" > 1.5< / span> & #x00a0 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. < span style=" font-style:normal font-weight:normal " class=" overriddenformat" > For specific warning statements, see Sections < span class=" Body-link1 cdone" > 7< / span> , < span class=" Body-link1 cdone" > 8< / span> , and < span class=" Body-link1 cdone" > 9< / span> < / span> .

< / div> < div class=" SectionLevel2" > < p class=" WTOcaveat cdone2" > < span class=" Head3 cdone" > 1.6< / span> & #x00a0 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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